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100 _a20210316a2018 k y0engy50 ba
101 0 _aeng
102 _aUS
105 _ay z 000zy
135 _adrgn ---uucaa
181 0 _ai
182 0 _ab
200 1 _aInfluence of UV-Activation of Modified Zeolite Catalysts on Their Physicochemical and Catalytic Properties in Their Process of Getting High-Octane Gasoline Components
_fI. S. Khomyakov, A. M. Gorshkov
203 _aText
_celectronic
300 _aTitle screen
320 _a[References: p. 14 (31 tit.)]
330 _aThe influence of UV-irradiation by an XeCl excimer lamp on the physicochemical and catalytic properties of MFI-type high-silica zeolites modified by cobalt tungsto- and molybdobismuthates in the process of getting high-octane gosoline components is studied. It is show that the concentration of acidic centers can be increased by 76%; the arene yield, by 4-13 wt%; and the octane number of the products, by 2-3 points as compared with starting zeolite if cobalt tungstobismuthate heteropoly compound (1 wt%) is used as the modifier and the material is activated by UV-irradiation for 24 min. It is established that UV-irradiation of modified zeolites increases the concentration of acidic centers and decreases the adsorption capacity and specific surface area.
333 _aРежим доступа: по договору с организацией-держателем ресурса
461 _tChemistry and Technology of Fuels and Oils
_d1965-
463 _tVol. 54, iss. 1
_v[P. 8-14]
_d2018
610 1 _aэлектронный ресурс
610 1 _aтруды учёных ТПУ
610 1 _aUV-irradiation
610 1 _aheteropoly compounds
610 1 _aMFI-type zeolite
610 1 _aaromatic hydrocarbons
610 1 _astraightrun gasoline
610 1 _ahighoctane components
610 1 _aУФ-облучение
610 1 _aпрямогонные бензины
610 1 _aвысокооктановые бензины
610 1 _aцеолиты
610 1 _aароматические углеводороды
700 1 _aKhomyakov
_bI. S.
_cSpecialist in the field of oil and gas business
_cSenior Lecturer of Tomsk Polytechnic University, candidate of chemical Sciences
_f1988-
_gIvan Sergeevich
_2stltpush
_3(RuTPU)RU\TPU\pers\32226
701 1 _aGorshkov
_bA. M.
_gAnton Mikhaylovich
712 0 2 _aНациональный исследовательский Томский политехнический университет
_bИнженерная школа природных ресурсов
_bОтделение нефтегазового дела
_h8084
_2stltpush
_3(RuTPU)RU\TPU\col\23546
801 2 _aRU
_b63413507
_c20210316
_gRCR
856 4 _uhttps://doi.org/10.1007/s10553-018-0891-1
942 _cCF