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001 664257
005 20231030041923.0
035 _a(RuTPU)RU\TPU\network\35441
090 _a664257
100 _a20210405a2019 k y0engy50 ba
101 0 _aeng
102 _aGB
135 _adrcn ---uucaa
181 0 _ai
182 0 _ab
200 1 _aFlexible plasmonic graphene oxide/heterostructures for dual-channel detection
_fV. Prakash, R. D. Rodriguez (Rodriges) Contreras, A. Al-Hamry [et al.]
203 _aText
_celectronic
300 _aTitle screen
320 _a[References: 53 tit.]
330 _aGraphene oxide (GO) films are deposited on flexible Kapton substrates and selectively modified to conductive reduced graphene oxide (rGO) electrodes using laser patterning. Based on this, we design, fabricate, and test a flexible sensor integrating laser-reduced GO with silver plasmonic nanostructures. The fabricated device results in dual transduction channels: for electrochemical and plasmonic nanostructure-based surface-enhanced Raman spectroscopy (SERS) detection. The spectroscopic analysis verifying the formation of rGO and the modification by silver nanostructures is performed by Raman, energy dispersive X-ray (EDX), and X-ray photoelectron spectroscopy (XPS). The morphological investigation is followed by optical and scanning electron microscopy imaging. In addition to pristine silver nanostructures, the Raman spectroscopy results show the formation of species such as Ag2O, Ag2CO3, and Ag2SOx. A dual-channel sensor device based on electrochemical and plasmonic detection is fabricated as a demonstration of our Ag–rGO flexible concept architecture. The dual-channel device performance is successfully demonstrated in the electrochemical and SERS detection of 4-nitrobenzenethiol (4-NBT) using the same device. Our results show that without Ag nanostructures the sensitivity in the electrochemical and optical channels is not sufficient to detect 4-NBT. The performance and stability of the silver modified device are also verified. This work demonstrates an inexpensive, highly efficient, and greener way that is compatible with solution-processing technology for the production of flexible GO-based electrochemical and SERS detection devices integrated with plasmonic nanostructures.
333 _aРежим доступа: по договору с организацией-держателем ресурса
461 _tAnalyst
463 _tVol. 144, iss. 10
_v[P. 3297-3306]
_d2019
610 1 _aэлектронный ресурс
610 1 _aтруды учёных ТПУ
701 1 _aPrakash
_bV.
_gVarnika
701 1 _aRodriguez (Rodriges) Contreras
_bR. D.
_cVenezuelan physicist, doctor of science
_cProfessor of Tomsk Polytechnic University
_f1982-
_gRaul David
_2stltpush
_3(RuTPU)RU\TPU\pers\39942
701 1 _aAl-Hamry
_bA.
_gAmmar
701 1 _aLipovka
_bA. A.
_cspecialist in the field of organization of higher vocational education
_cengineer of Tomsk Polytechnic University
_f1993-
_gAnna Anatolyevna
_2stltpush
_3(RuTPU)RU\TPU\pers\44078
701 1 _aDorozhko
_bE. V.
_cchemist
_cEngineer of Tomsk Polytechnic University
_f1979-
_gElena Vladimirovna
_2stltpush
_3(RuTPU)RU\TPU\pers\32174
701 1 _aSelyshchev
_bO.
_gOleksandr
701 0 _aMa Bing
701 1 _aSharma
_bS.
_gShweta
701 1 _aMehta
_bS. K.
_gSurinder Kumar
701 1 _aDzhagan
_bV.
_gVolodymyr
701 1 _aMukherjee
_bA.
_gAshutosh
701 1 _aZahn Dietrich
_bR. T.
701 1 _aKanoun
_bO.
_gOlfa
701 1 _aSheremet
_bE. S.
_cphysicist
_cProfessor of Tomsk Polytechnic University
_f1988-
_gEvgeniya Sergeevna
_2stltpush
_3(RuTPU)RU\TPU\pers\40027
712 0 2 _aНациональный исследовательский Томский политехнический университет
_bИсследовательская школа физики высокоэнергетических процессов
_c(2017- )
_h8118
_2stltpush
_3(RuTPU)RU\TPU\col\23551
801 2 _aRU
_b63413507
_c20210405
_gRCR
856 4 _uhttps://doi.org/10.1039/C8AN02495B
942 _cCF