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001 | 664265 | ||
005 | 20231030041923.0 | ||
035 | _a(RuTPU)RU\TPU\network\35449 | ||
090 | _a664265 | ||
100 | _a20210406a2019 k y0engy50 ba | ||
101 | 0 | _aeng | |
102 | _aNL | ||
135 | _adrcn ---uucaa | ||
181 | 0 | _ai | |
182 | 0 | _ab | |
200 | 1 |
_aCyclic stability of the C36-type TiCr2 Laves phase synthesized in the abnormal glow discharge plasma under hydrogenation _fT. L. Murashkina, M. S. Syrtanov, R. S. Laptev, A. M. Lider |
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203 |
_aText _celectronic |
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300 | _aTitle screen | ||
320 | _a[References: 41 tit.] | ||
330 | _aIn this work, the cyclic stability of the C36-type TiCr2 Laves phase synthesized in the abnormal glow discharge plasma was investigated. Melting of titanium-chromium metallic powders by the glow discharge plasma leads to the formation of the TiCr2 hexagonal C36 Laves phase with lattice parameters a = 4.928 A and c = 15.983 A. The hydrogenation-dehydrogenation method was used for crushing to increase the effective sorption capacity of the C36-type TiCr2 Laves phase. The stable hydride TiCr2Hx (x ? 0.5) phase of structural polytype C36 is formed during the first absorption/desorption cycle at the temperature of 30 °C. After 15 cycles hydride with the stoichiometric composition close to the TiCr2H0.5 phase of C36 polytype with lattice parameters: a = 4.961 A and c = 16.224 A was observed by XRD analysis. The hydrogen is localized in the crystal lattice in three main states: in a solid solution trapped by defects, open volume defects, and in the form of hydrides. | ||
333 | _aРежим доступа: по договору с организацией-держателем ресурса | ||
461 | _tInternational Journal of Hydrogen Energy | ||
463 |
_tVol. 44, iss. 13 _v[P. 6709-6719] _d2019 |
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610 | 1 | _aэлектронный ресурс | |
610 | 1 | _aтруды учёных ТПУ | |
610 | 1 | _alaves phase | |
610 | 1 | _ahydrogen storage | |
610 | 1 | _aglow discharge | |
610 | 1 | _aTi-Cr alloys | |
610 | 1 | _ahydrogenation | |
610 | 1 | _athermal desorption spectroscopy | |
701 | 1 |
_aMurashkina _bT. L. _cPhysicist _cEngineer of Tomsk Polytechnic University, Assistant _f1990- _gTatiana Leonidovna _2stltpush _3(RuTPU)RU\TPU\pers\39441 |
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701 | 1 |
_aSyrtanov _bM. S. _cphysicist _cengineer of Tomsk Polytechnic University _f1990- _gMaksim Sergeevich _2stltpush _3(RuTPU)RU\TPU\pers\34764 |
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701 | 1 |
_aLaptev _bR. S. _cphysicist, specialist in the field of non-destructive testing _cAssociate Scientist of Tomsk Polytechnic University, Assistant, Candidate of Sciences _f1987- _gRoman Sergeevich _2stltpush _3(RuTPU)RU\TPU\pers\31884 |
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701 | 1 |
_aLider _bA. M. _cPhysicist _cAssociate Professor of Tomsk Polytechnic University, Candidate of Physical and Mathematical Sciences (PhD) _f1976- _gAndrey Markovich _2stltpush _3(RuTPU)RU\TPU\pers\30400 |
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712 | 0 | 2 |
_aНациональный исследовательский Томский политехнический университет _bИнженерная школа ядерных технологий _bОтделение экспериментальной физики _h7865 _2stltpush _3(RuTPU)RU\TPU\col\23549 |
801 | 2 |
_aRU _b63413507 _c20210406 _gRCR |
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856 | 4 | _uhttps://doi.org/10.1016/j.ijhydene.2019.01.150 | |
942 | _cCF |