| 000 | 03639nlm1a2200481 4500 | ||
|---|---|---|---|
| 001 | 664300 | ||
| 005 | 20231030041924.0 | ||
| 035 | _a(RuTPU)RU\TPU\network\35484 | ||
| 090 | _a664300 | ||
| 100 | _a20210407a2020 k y0engy50 ba | ||
| 101 | 0 | _aeng | |
| 102 | _aUS | ||
| 135 | _adrcn ---uucaa | ||
| 181 | 0 | _ai | |
| 182 | 0 | _ab | |
| 200 | 1 |
_aApplication of a 2D Molybdenum Telluride in SERS Detection of Biorelevant Molecules _fJ. P. Fraser, P. S. Postnikov, E. V. Milyutina (Miliutina) [et al.] |
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| 203 |
_aText _celectronic |
||
| 300 | _aTitle screen | ||
| 320 | _a[References: 53 tit.] | ||
| 330 | _aTwo-dimensional (2D) transition-metal dichalcogenides have become promising candidates for surface-enhanced Raman spectroscopy (SERS), but currently very few examples of detection of relevant molecules are available. Herein, we show the detection of the lipophilic disease marker ?-sitosterol on few-layered MoTe2 films. The chemical vapor deposition (CVD)-grown films are capable of nanomolar detection, exceeding the performance of alternative noble-metal surfaces. We confirm that the enhancement occurs through the chemical enhancement (CE) mechanism via formation of a surface–analyte complex, which leads to an enhancement factor of ?104, as confirmed by Fourier transform infrared (FTIR), UV–vis, and cyclic voltammetry (CV) analyses and density functional theory (DFT) calculations. Low values of signal deviation over a seven-layered MoTe2 film confirms the homogeneity and reproducibility of the results in comparison to noble-metal substrate analogues. Furthermore, ?-sitosterol detection within cell culture media, a minimal loss of signal over 50 days, and the opportunity for sensor regeneration suggest that MoTe2 can become a promising new SERS platform for biosensing. | ||
| 333 | _aРежим доступа: по договору с организацией-держателем ресурса | ||
| 461 | _tACS Applied Materials and Interfaces | ||
| 463 |
_tVol. 12, iss. 42 _v[P. 47774–47783] _d2020 |
||
| 610 | 1 | _aэлектронный ресурс | |
| 610 | 1 | _aтруды учёных ТПУ | |
| 610 | 1 | _aMoTe2 | |
| 610 | 1 | _aSERS | |
| 610 | 1 | _asensing | |
| 610 | 1 | _achemical enhancement | |
| 610 | 1 | _aβ-sitosterol | |
| 701 | 1 |
_aFraser _bJ. P. _gJames |
|
| 701 | 1 |
_aPostnikov _bP. S. _corganic chemist _cAssociate Professor of Tomsk Polytechnic University, Candidate of chemical sciences _f1984- _gPavel Sergeevich _2stltpush _3(RuTPU)RU\TPU\pers\31287 |
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| 701 | 1 |
_aMilyutina (Miliutina) _bE. V. _cchemical technologist _cengineer of Tomsk Polytechnic University _f1991- _gElena Vadimovna _2stltpush _3(RuTPU)RU\TPU\pers\46756 |
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| 701 | 1 |
_aKolska _bZ. _gZdenka |
|
| 701 | 1 |
_aValiev _bR. R. _cchemist _cAssistant of Tomsk Polytechnic University _f1983- _gRashid Rinatovich _2stltpush _3(RuTPU)RU\TPU\pers\34114 |
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| 701 | 1 |
_aSvorcik _bV. _gVaclav |
|
| 701 | 1 |
_aLyutakov _bO. _cchemist-technologist _cAssociate Scientist of Tomsk Polytechnic University _f1982- _gOleksy _2stltpush _3(RuTPU)RU\TPU\pers\36875 |
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| 701 | 1 |
_aGanin _bA. Y. _gAlexey |
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| 701 | 1 |
_aGuselnikova _bO. A. _cchemist _cengineer of Tomsk Polytechnic University _f1992- _gOlga Andreevna _2stltpush _3(RuTPU)RU\TPU\pers\34478 |
|
| 712 | 0 | 2 |
_aНациональный исследовательский Томский политехнический университет _bИсследовательская школа химических и биомедицинских технологий _c(2017- ) _h8120 _2stltpush _3(RuTPU)RU\TPU\col\23537 |
| 801 | 2 |
_aRU _b63413507 _c20210409 _gRCR |
|
| 856 | 4 | _uhttps://doi.org/10.1021/acsami.0c11231 | |
| 942 | _cCF | ||