| 000 | 02722nlm1a2200397 4500 | ||
|---|---|---|---|
| 001 | 664699 | ||
| 005 | 20231030041938.0 | ||
| 035 | _a(RuTPU)RU\TPU\network\35883 | ||
| 035 | _aRU\TPU\network\35645 | ||
| 090 | _a664699 | ||
| 100 | _a20210514a2021 k y0engy50 ba | ||
| 101 | 0 | _aeng | |
| 135 | _adrcn ---uucaa | ||
| 181 | 0 | _ai | |
| 182 | 0 | _ab | |
| 200 | 1 |
_aAn Analysis of Vibrations and Rotations in the First Hydrogen Sulfide Hexade: the 4ν2 H322S Band _fZhang Fangce, N. I. Raspopova |
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| 203 |
_aText _celectronic |
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| 300 | _aTitle screen | ||
| 320 | _a[References: 16 tit.] | ||
| 330 | _aThe infrared spectrum of the H2S molecule is recorded using a Bruker IFS 125HR Fourier transform spectrometer and studied in the range of 4500-5000 cm-1, in which the first hexad of bands of interacting states of the hydrogen sulfide molecule is located (in this particular case, weak band 4ν2ν2 is studied). Four hundred transitions with maximum quantum numbers of JmaxJmax = 17 and KmaxaKamax = 8 are assigned in the experimental spectrum. These transitions correspond to one hundred thirty two upper vibration-rotation energy levels. The obtained data are analyzed using Watson's model of the effective Hamiltonian. By solving the inverse spectroscopic problem, a set of twenty eight spectroscopic parameters was obtained, which reproduces the initial experimental data with a standard deviation of drmsdrms= 3.5 × 10-4 cm-1. | ||
| 333 | _aРежим доступа: по договору с организацией-держателем ресурса | ||
| 461 | _tOptics and Spectroscopy | ||
| 463 |
_tVol. 129, iss. 1 _v[P. 6-11] _d2021 |
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| 610 | 1 | _aэлектронный ресурс | |
| 610 | 1 | _aтруды учёных ТПУ | |
| 610 | 1 | _amolecular spectroscopy | |
| 610 | 1 | _afirst hydrogen sulfide hexade | |
| 610 | 1 | _avibration-rotation Hamiltonian | |
| 610 | 1 | _aмолекулярная спектроскопия | |
| 610 | 1 | _aгамильтонианы | |
| 700 | 0 |
_aZhang Fangce _cChinese physicist _ctechnician of Tomsk Polytechnic University _f1993- _2stltpush _3(RuTPU)RU\TPU\pers\42500 |
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| 701 | 1 |
_aRaspopova _bN. I. _cphysicist _cTechnician of Tomsk Polytechnic University, Assistant of the Department _f1990- _gNatalya Ivanovna _2stltpush _3(RuTPU)RU\TPU\pers\34080 |
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| 712 | 0 | 2 |
_aНациональный исследовательский Томский политехнический университет _bИсследовательская школа физики высокоэнергетических процессов _c(2017- ) _h8118 _2stltpush _3(RuTPU)RU\TPU\col\23551 |
| 801 | 2 |
_aRU _b63413507 _c20210514 _gRCR |
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| 856 | 4 | 0 | _uhttps://doi.org/10.1134/S0030400X21010045 |
| 942 | _cCF | ||