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100 _a20210525a2019 k y0engy50 ba
101 0 _aeng
135 _adrcn ---uucaa
181 0 _ai
182 0 _ab
200 1 _aStructural and optical study of Zn-doped As2Se3 thin films: Evidence for photoinduced formation of ZnSe nanocrystallites
_fYu. M. Azhniuk, D. I. Solonenko, E. S. Sheremet [et al.]
203 _aText
_celectronic
300 _aTitle screen
320 _a[References: 79 tit.]
330 _aAmorphous Zn-doped As2Se3 films with a nominal zinc content x up to 10 at.% were prepared by thermal evaporation. Their structure is characterized by atomic force microscopy (AFM), scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDX), X-ray photoemission spectroscopy (XPS), and Raman spectroscopy. The AFM data show a considerable increase of the film surface roughness for films with x > 5 at.%. A strong gradient of the Zn content decreasing into the film depth is confirmed by the EDX and XPS data. Heavily Zn-doped (above 7 at.%) As2Se3 films reveal photostructural changes in the course of the Raman measurements. New Raman features are attributed to TO and LO vibrations of ZnSe nanocrystallites formed in the film under laser illumination. Depending on the laser wavelength and power density, the ZnSe nanocrystallites can experience tensile strain in the film due to a non-thermal photoplastic effect in the As2Se3 film resulting in a partial removal of the material from the laser spot. The tensile strain value, estimated from the TO and LO phonon frequency shift, is shown to reach up to 2.9 GPa
333 _aРежим доступа: по договору с организацией-держателем ресурса
461 _tAIP Advances
463 _tVol. 9, iss. 6
_v[065212, 14 p.]
_d2019
610 1 _aэлектронный ресурс
610 1 _aтруды учёных ТПУ
701 1 _aAzhniuk
_bYu. M.
701 1 _aSolonenko
_bD. I.
_gDmytro
701 1 _aSheremet
_bE. S.
_cphysicist
_cProfessor of Tomsk Polytechnic University
_f1988-
_gEvgeniya Sergeevna
_2stltpush
_3(RuTPU)RU\TPU\pers\40027
701 1 _aDzhagan
_bV.
_gVolodymyr
701 1 _aLoya
_bV. Yu.
_gVasyl
701 1 _aGrytsyshche
_bI. V.
_gIaroslav
701 1 _aSchulze
_bS.
_gSteffen
701 1 _aHietschold
_bM.
_gMichael
701 1 _aGomonnai
_bA. V.
_gAlexander
701 1 _aZahn
_bD. R. T.
_gDietrich
712 0 2 _aНациональный исследовательский Томский политехнический университет
_bИсследовательская школа физики высокоэнергетических процессов
_c(2017- )
_h8118
_2stltpush
_3(RuTPU)RU\TPU\col\23551
801 2 _aRU
_b63413507
_c20210525
_gRCR
856 4 0 _uhttps://doi.org/10.1063/1.5086974
942 _cCF