| 000 | 03535nlm1a2200469 4500 | ||
|---|---|---|---|
| 001 | 664905 | ||
| 005 | 20231030041945.0 | ||
| 035 | _a(RuTPU)RU\TPU\network\36090 | ||
| 035 | _aRU\TPU\network\26672 | ||
| 090 | _a664905 | ||
| 100 | _a20210528a2012 k y0engy50 ba | ||
| 101 | 0 | _aeng | |
| 135 | _adrcn ---uucaa | ||
| 181 | 0 | _ai | |
| 182 | 0 | _ab | |
| 200 | 1 |
_aApplication of a voltammetric method for investigation the formation mechanisms of silver nanoparticles in multicomponent solutions _fG. V. Lyamina, O. V. Kamchatnaya, A. Yu. Plotnikova [et al.] |
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| 203 |
_aText _celectronic |
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| 300 | _aTitle screen | ||
| 320 | _a[References: 26 tit.] | ||
| 330 | _aA voltammetric method has been tested for the investigation of the kinetics of formation of silver nanoparticles in two systems: (a) silver(I) triflourineacetate, methylcellosolve, butyl acetate, toluene and methyl methacrylate with methacrylic acid copolymer; and (b) silver nitrate, sodium citrate, poly-N-vinyl-2-pirrolydone, sodium borohydride. It could be established for the first system that the formation rate of metal nanoparticles from silver triflourineacetate solutions depends on the dielectric constant and complexing ability of the solvent. The formation of silver particles proceeds faster in methylcellosolve than in other solvents. The butyl acetate addition to the solution contributes to the complex stability of methylcellosolve with silver triflourineacetate and decelerates the formation process of particles. It could be shown that nitrogen purging of solutions containing poly-N-vinyl-2-pirrolydone affects the silver-ion concentration in the first stage of synthesis and accelerates the formation process of nanoparticles for the second system. The spherical silver nanoparticles which are formed at the first stage of the synthesis are destroyed after starting the UV–irradiation. Then new silver nanoparticles (triangular prisms) are formed. | ||
| 333 | _aРежим доступа: по договору с организацией-держателем ресурса | ||
| 461 | _tJournal of Solid State Electrochemistry | ||
| 463 |
_tVol. 16, iss. 7 _v[P. 2473–2480] _d2012 |
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| 610 | 1 | _aэлектронный ресурс | |
| 610 | 1 | _aтруды учёных ТПУ | |
| 610 | 1 | _aelectrochemistry | |
| 610 | 1 | _asilver nanoparticles | |
| 610 | 1 | _aphase boundary properties | |
| 610 | 1 | _apolymer materials | |
| 610 | 1 | _aэлектрохимия | |
| 610 | 1 | _aнаночастицы | |
| 610 | 1 | _aполимерные материалы | |
| 701 | 1 |
_aLyamina _bG. V. _cchemist _cAssociate Professor of Tomsk Polytechnic University, Candidate of chemical sciences _f1974- _gGalina Vladimirovna _2stltpush _3(RuTPU)RU\TPU\pers\34501 |
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| 701 | 1 |
_aKamchatnaya _bO. V. _cspecialist in the field of material science _cAssociate Professor of Tomsk Polytechnic University, Candidate of chemical sciences _f1984- _gOksana Valerievna _2stltpush _3(RuTPU)RU\TPU\pers\46876 |
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| 701 | 1 |
_aPlotnikova _bA. Yu. |
|
| 701 | 1 |
_aIzaak _bT. I. |
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| 701 | 1 |
_aAnishenko _bE. V. |
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| 701 | 1 |
_aMokrousov _bG. M. |
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| 712 | 0 | 2 |
_aНациональный исследовательский Томский политехнический университет _bИнститут физики высоких технологий _bКафедра наноматериалов и нанотехнологий _h4572 _2stltpush _3(RuTPU)RU\TPU\col\18685 |
| 801 | 2 |
_aRU _b63413507 _c20210528 _gRCR |
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| 856 | 4 | 0 | _uhttps://doi.org/10.1007/s10008-012-1788-2 |
| 942 | _cCF | ||