| 000 | 02808nlm1a2200445 4500 | ||
|---|---|---|---|
| 001 | 665032 | ||
| 005 | 20231030041949.0 | ||
| 035 | _a(RuTPU)RU\TPU\network\36231 | ||
| 090 | _a665032 | ||
| 100 | _a20210624a2020 k y0engy50 ba | ||
| 101 | 0 | _aeng | |
| 135 | _adrcn ---uucaa | ||
| 181 | 0 | _ai | |
| 182 | 0 | _ab | |
| 200 | 1 |
_aMIL-101(Cr) for CO2 Conversion into Cyclic Carbonates, Under Solvent and Co-Catalyst Free Mild Reaction Conditions _fE. Akimana, J. Wang, N. V. Likhanova [et al.] |
|
| 203 |
_aText _celectronic |
||
| 300 | _aTitle screen | ||
| 320 | _a[References: 53 tit.] | ||
| 330 | _aMild reaction conditions (nearly room temperature and atmospheric CO2 pressure) for the cycloaddition of CO2 with epoxides to produce cyclic carbonates were investigated applying MIL-101(Cr) as a catalyst. The MIL-101 catalyst contains strong acid sites, which promote the ring-opening of the epoxide substrate. Moreover, the high surface area, enabling the adsorption of more CO2 (substrate), combined with a large pore size of the catalyst is essential for the catalytic performance. Additionally, epoxide substrates bearing electron-withdrawing substituents or having a low boiling point demonstrated an excellent conversion towards the cyclic carbonates. MIL-101(Cr) for the cycloaddition of carbon dioxide with epoxides is demonstrated to be a robust and stable catalyst able to be re-used at least five times without loss in activity. | ||
| 461 | _tCatalysts | ||
| 463 |
_tVol. 10, iss. 4 _v[453, 12 p.] _d2020 |
||
| 610 | 1 | _aэлектронный ресурс | |
| 610 | 1 | _aтруды учёных ТПУ | |
| 610 | 1 | _aMIL-101 | |
| 610 | 1 | _aheterogeneous catalyst | |
| 610 | 1 | _aCO2 cycloaddition | |
| 610 | 1 | _acarbonate | |
| 610 | 1 | _aambient conditions | |
| 610 | 1 | _aгетерогенные катализаторы | |
| 610 | 1 | _aкарбонаты | |
| 610 | 1 | _aокружающая среда | |
| 701 | 1 |
_aAkimana _bE. _gEmmanuelia |
|
| 701 | 1 |
_aWang _bJ. _gJichao |
|
| 701 | 1 |
_aLikhanova _bN. V. _gNataljya Vladimirovna |
|
| 701 | 0 |
_aChaemchuen Somboon _cchemist-technologist _cresearcher at Tomsk Polytechnic University, Ph.D _f1984- _2stltpush _3(RuTPU)RU\TPU\pers\42620 |
|
| 701 | 1 |
_aVerpoort _bF. V. K. _cChemical Engineer _cProfessor of Tomsk Polytechnic University, doctor of chemical Sciences _f1963- _gFrensis Valter Kornelius _2stltpush _3(RuTPU)RU\TPU\pers\35059 |
|
| 712 | 0 | 2 |
_aНациональный исследовательский Томский политехнический университет _bИсследовательская школа химических и биомедицинских технологий _c(2017- ) _h8120 _2stltpush _3(RuTPU)RU\TPU\col\23537 |
| 801 | 2 |
_aRU _b63413507 _c20210624 _gRCR |
|
| 856 | 4 | _uhttps://doi.org/10.3390/catal10040453 | |
| 942 | _cCF | ||