| 000 | 03182nlm1a2200493 4500 | ||
|---|---|---|---|
| 001 | 665249 | ||
| 005 | 20231030041956.0 | ||
| 035 | _a(RuTPU)RU\TPU\network\36448 | ||
| 035 | _aRU\TPU\network\29080 | ||
| 090 | _a665249 | ||
| 100 | _a20210906a2020 k y0engy50 ba | ||
| 101 | 0 | _aeng | |
| 135 | _adrcn ---uucaa | ||
| 181 | 0 | _ai | |
| 182 | 0 | _ab | |
| 200 | 1 |
_aA Cu-based MOF for the effective carboxylation of terminal alkynes with CO2 under mild conditions _fShia Guangyong, Xu Wei, Wang Jichao [et al.] |
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| 203 |
_aText _celectronic |
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| 300 | _aTitle screen | ||
| 320 | _a[References: 40 tit.] | ||
| 330 | _aThe coordination of pyridylcarboxylate (isonicotinic acid, IN) with copper (II) fabricates a Cu(IN)-MOF. The characteristic properties of the Cu(IN)-MOF are obtained via different analysis techniques such as XRD, SEM, BET, ICP, TG, etc. The advantage of copper(II) coordinated with a bi-functional organic linker (IN), containing a pyridyl and carboxylate group, is demonstrated by the chemical properties of which the Cu(II)-based MOF exhibits excellent catalytic performance for the CO2 carboxylation of terminal alkynes. No noble-metal, co-catalyst, or additives are required to execute the reaction. The effectiveness of the Cu(IN)-MOF was demonstrated with a variety of substrates (>11). Moreover, the Cu(IN)-MOF, as a heterogeneous catalyst, can be recycled at least 5 times retaining its excellent catalytic performance. Herein, we report the first copper (II) metal-organic framework (Cu(IN)-MOF) applied for the carboxylation of alkynes with CO2 demonstrating several advantages such as stable catalyst, avoiding the use of an expensive noble-metal, straightforward synthesis. | ||
| 333 | _aРежим доступа: по договору с организацией-держателем ресурса | ||
| 461 | _tJournal of CO2 Utilization | ||
| 463 |
_tVol. 39 _v[101177, 7 p.] _d2020 |
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| 610 | 1 | _aэлектронный ресурс | |
| 610 | 1 | _aтруды учёных ТПУ | |
| 610 | 1 | _aMOF | |
| 610 | 1 | _acarbon dioxide | |
| 610 | 1 | _acarboxylation | |
| 610 | 1 | _aalkynes | |
| 610 | 1 | _acopper | |
| 610 | 1 | _aуглекислый газ | |
| 610 | 1 | _aкарбоксилирование | |
| 610 | 1 | _aалкины | |
| 610 | 1 | _aмедь | |
| 701 | 0 | _aShia Guangyong | |
| 701 | 0 | _aXu Wei | |
| 701 | 0 | _aWang Jichao | |
| 701 | 0 | _aYuan Ye | |
| 701 | 0 |
_aChaemchuen Somboon _cchemist-technologist _cresearcher at Tomsk Polytechnic University, Ph.D _f1984- _2stltpush _3(RuTPU)RU\TPU\pers\42620 |
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| 701 | 1 |
_aVerpoort _bF. V. K. _cchemist-technologist _cProfessor of Tomsk Polytechnic University, doctor of chemical Sciences _f1963- _gFrensis Valter Kornelius _2stltpush _3(RuTPU)RU\TPU\pers\35059 |
|
| 712 | 0 | 2 |
_aНациональный исследовательский Томский политехнический университет _bИсследовательская школа химических и биомедицинских технологий (ИШХБМТ) _c(2017- ) _h8120 _2stltpush _3(RuTPU)RU\TPU\col\23537 |
| 801 | 2 |
_aRU _b63413507 _c20210906 _gRCR |
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| 856 | 4 | _uhttps://doi.org/10.1016/j.jcou.2020.101177 | |
| 942 | _cCF | ||