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100 _a20210913a2021 k y0engy50 ba
101 0 _aeng
102 _aCH
135 _adrcn ---uucaa
181 0 _ai
182 0 _ab
200 1 _aOptical pH Sensing in Milk: A Small Puzzle of Indicator Concentrations and the Best Detection Method
_fO. B. Voskoboynikova, A. V. Sukhanov, A. Duerkop
203 _aText
_celectronic
300 _aTitle screen
320 _a[References: 31 tit.]
330 _aOptical chemical sensors can yield distinctively different responses that are dependent on the method applied for readout and evaluation. We therefore present a comprehensive study on the pH determined non-continuously with optical sensors in real milk samples by either photometry or colorimetry (via the RGB-readout of digital images) compared to the pH values obtained electrochemically by potentiometry. Additionally, the photometric determination of pH was conducted with single-wavelength and a dual wavelength ratiometric evaluation of the absorbance. It was found that both the precision and accuracy of the pH determined by photometry benefit from lower concentrations of bromocresol purple, which served as the pH indicator inside the sensor membrane. A further improvement is obtained by the ratiometric evaluation of the photometric sensor response. The pH values obtained from the colorimetric evaluation, however, gain in precision and accuracy if a higher concentration of the indicator is immobilized inside the sensor membrane. This has a major impact on the future fabrication of optical pH sensor membranes because they can be better tuned to match to the most precise and accurate range of the planned detection method.
461 _tChemosensors
463 _tVol. 9, iss. 7
_v[177, 9 p.]
_d2021
610 1 _aэлектронный ресурс
610 1 _aтруды учёных ТПУ
610 1 _apH sensor
610 1 _aoptical
610 1 _aphotometry
610 1 _acolorimetry
610 1 _apotentiometry
610 1 _adigital image
610 1 _aдатчики
610 1 _aфотометрия
610 1 _aколориметрия
610 1 _aпотенциометрия
610 1 _aцифровые изображения
700 1 _aVoskoboynikova
_bO. B.
_cSpecialist in the field of informatics and computer technology
_cSenior Lecturer of Tomsk Polytechnic University
_f1990-
_gOlga Borisovna
_2stltpush
_3(RuTPU)RU\TPU\pers\46955
701 1 _aSukhanov
_bA. V.
_cspecialist in the field of scientific activity
_cLeading expert of Tomsk Polytechnic University, Candidate of chemical sciences
_f1983-
_gAleksey Viktorovich
_2stltpush
_3(RuTPU)RU\TPU\pers\31389
701 1 _aDuerkop
_bA.
_gAxel
712 0 2 _aНациональный исследовательский Томский политехнический университет
_bИнженерная школа информационных технологий и робототехники
_bОтделение автоматизации и робототехники
_h7952
_2stltpush
_3(RuTPU)RU\TPU\col\23553
801 2 _aRU
_b63413507
_c20211209
_gRCR
856 4 _uhttp://earchive.tpu.ru/handle/11683/69111
856 4 _uhttps://doi.org/10.3390/chemosensors9070177
942 _cCF