| 000 | 03600nlm1a2200517 4500 | ||
|---|---|---|---|
| 001 | 665407 | ||
| 005 | 20231030042002.0 | ||
| 035 | _a(RuTPU)RU\TPU\network\36606 | ||
| 035 | _aRU\TPU\network\35016 | ||
| 090 | _a665407 | ||
| 100 | _a20210923a2021 k y0engy50 ba | ||
| 101 | 0 | _aeng | |
| 102 | _aCH | ||
| 135 | _adrcn ---uucaa | ||
| 181 | 0 | _ai | |
| 182 | 0 | _ab | |
| 200 | 1 |
_aEffect of the Metal Deposition Order on Structural, Electronic and Catalytic Properties of TiO2-Supported Bimetallic Au-Ag Catalysts in 1-Octanol Selective Oxidation _fYu. Kotolevich, E. G. Pakrieva, E. N. Kolobova [et al.] |
|
| 203 |
_aText _celectronic |
||
| 300 | _aTitle screen | ||
| 320 | _a[References: 83 tit.] | ||
| 330 | _aAu and Ag were deposited on TiO2 modified with Ce, La, Fe or Mg in order to obtain bimetallic catalysts to be used for liquid-phase oxidation of 1-octanol. The effects of the deposition order of gold and silver, and the nature of the support modifying additives and redox pretreatments on the catalytic properties of the bimetallic Au-Ag catalysts were studied. Catalysts were characterized by low-temperature nitrogen adsorption–desorption, energy dispersive spectroscopy, X-ray diffraction, X-ray photoelectron spectroscopy, high-resolution transmission electron microscopy and ultraviolet-visible diffuse reflectance spectroscopy. It was found that pretreatments with hydrogen and oxygen at 300 °C significantly decreased the activity of AuAg catalysts (silver was deposited first) and had little effect on the catalytic properties of AgAu samples (gold was deposited first). The density functional theory method demonstrated that the adsorption energy of 1-octanol increased for all positively charged AuxAgyq (x + y = 10, with a charge of q = 0 or +1) clusters compared with the neutral counterparts. Lanthanum oxide was a very effective promoter for both monometallic and bimetallic gold and silver catalysts in the studied process. | ||
| 461 | _tCatalysts | ||
| 463 |
_tVol. 11, iss. 7 _v[799, 18 p.] _d2021 |
||
| 610 | 1 | _aэлектронный ресурс | |
| 610 | 1 | _aтруды учёных ТПУ | |
| 610 | 1 | _agold | |
| 610 | 1 | _asilver | |
| 610 | 1 | _abimetallic catalysts | |
| 610 | 1 | _a1-octanol oxidation | |
| 610 | 1 | _aзолото | |
| 610 | 1 | _aбиметаллические катализаторы | |
| 610 | 1 | _aокисление | |
| 701 | 1 |
_aKotolevich _bYu. _gYulia |
|
| 701 | 1 |
_aPakrieva _bE. G. _cChemical Engineer _cEngineer of Tomsk Polytechnic University _f1989- _gEkaterina Germanovna _2stltpush _3(RuTPU)RU\TPU\pers\33273 |
|
| 701 | 1 |
_aKolobova _bE. N. _cChemical Engineer _cdesign engineer of Tomsk Polytechnic University _f1989- _gEkaterina Nikolaevna _2stltpush _3(RuTPU)RU\TPU\pers\34488 |
|
| 701 | 1 |
_aFarias _bM. H. _gMario |
|
| 701 | 1 |
_aBogdanchikova _bN. _gNina |
|
| 701 | 1 |
_aCorberan _bV. C. _gCortes |
|
| 701 | 1 |
_aPichugina _bD. A. _gDaria |
|
| 701 | 1 |
_aNikitina _bN. A. _gNadezhda |
|
| 701 | 1 |
_aCarabineiro _bS. A. C. _gSonia Alexandra Correia |
|
| 701 | 1 |
_aPestryakov _bA. N. _cChemist _cProfessor of Tomsk Polytechnic University, Doctor of Chemical Science _f1963- _gAleksey Nikolaevich _2stltpush _3(RuTPU)RU\TPU\pers\30471 |
|
| 712 | 0 | 2 |
_aНациональный исследовательский Томский политехнический университет _bИсследовательская школа химических и биомедицинских технологий _c(2017- ) _h8120 _2stltpush _3(RuTPU)RU\TPU\col\23537 |
| 801 | 2 |
_aRU _b63413507 _c20210923 _gRCR |
|
| 856 | 4 | _uhttps://doi.org/10.3390/catal11070799 | |
| 942 | _cCF | ||