| 000 | 04082nlm1a2200481 4500 | ||
|---|---|---|---|
| 001 | 665703 | ||
| 005 | 20231030042012.0 | ||
| 035 | _a(RuTPU)RU\TPU\network\36907 | ||
| 035 | _aRU\TPU\network\35105 | ||
| 090 | _a665703 | ||
| 100 | _a20211109a2021 k y0engy50 ba | ||
| 101 | 0 | _aeng | |
| 135 | _adrcn ---uucaa | ||
| 181 | 0 | _ai | |
| 182 | 0 | _ab | |
| 200 | 1 |
_aFluorite Formation in Poplar Leaves (Populus balsamifera L.) in an HF-Polluted Area _fD. V. Yusupov, L. A. Dorokhova, S. S. Iljenok (Il'enok) [et al.] |
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| 203 |
_aText _celectronic |
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| 300 | _aTitle screen | ||
| 330 | _aThe article represents results of the study aimed on sensitivity of balsam poplar (Populus balsamifera L.) leaves to hydrogen fluoride airborne emissions in the vicinity of aluminum smelter. Widespread occurrence of poplar in urban land was one of the purposes to choose this plant as a research object. Reaction of poplar leaves on influence of hydrogen fluoride (HF) was investigated by ionometric technique, scanning electron microscopy-related method (SEM–EDS), X-ray diffraction analysis (XRD), and the thermodynamic modelling. The fluoride content in poplar leaves decreases with distance from the emission source. Leaves have signs of deterioration, e.g., chemical burns and necrosis, inside 2-km zone of the plant. In stomatal cells of poplar leaves, neogenic mineral fluorite (CaF2) was discovered. In sieve-tube elements of leaf phloem, a large quantity of secondary calcite (CaCO3) crystals was found. Ca2+ ions in enchylema react with F- that has released as part of airborne emissions from aluminum smelter. Result of their interaction is fluorite formation in stomatal cells of poplar leaves. Such fluorite is a mineral indicator of fluoride pollution in ground-level ambient air. Thermodynamic conditions of interaction of Ca2+ and F–, HCO3– and Ca2+ were estimated. The model of maintenance of phytochemical calcium barrier in the poplar leaves stomata in HF contamination was proposed and described. | ||
| 333 | _aРежим доступа: по договору с организацией-держателем ресурса | ||
| 461 | _tWater, Air, & Soil Pollution | ||
| 463 |
_tVol. 232, iss. 9 _v[369, 14 p.] _d2021 |
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| 610 | 1 | _aэлектронный ресурс | |
| 610 | 1 | _aтруды учёных ТПУ | |
| 610 | 1 | _apoplars leaves | |
| 610 | 1 | _astomata | |
| 610 | 1 | _afluorite | |
| 610 | 1 | _acalcite | |
| 610 | 1 | _aSEM-EDS | |
| 610 | 1 | _aXRD | |
| 701 | 1 |
_aYusupov _bD. V. _cgeologist _cAssociate Professor of Tomsk Polytechnic University, Candidate of geological and mineralogical sciences _f1977- _gDmitry Valerievich _2stltpush _3(RuTPU)RU\TPU\pers\32832 |
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| 701 | 1 |
_aDorokhova _bL. A. _gLyubov Aleksandrovna |
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| 701 | 1 |
_aIljenok (Il'enok) _bS. S. _cgeochemist _cassistant Professor of Tomsk Polytechnic Institute _f1986- _gSergey Sergeevich _2stltpush _3(RuTPU)RU\TPU\pers\35195 |
|
| 701 | 1 |
_aRadomskaya _bV. I. _gValentina Ivanovna |
|
| 701 | 1 |
_aPavlova _bL. M. _gLyudmila Mikhaylovna |
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| 701 | 1 |
_aKraydenko (Kraidenko) _bR. I. _cChemical Engineer _cAssociate Professor of Tomsk Polytechnic University, Senior Researcher, Candidate of chemical sciences _f1983- _gRoman Ivanovich _2stltpush _3(RuTPU)RU\TPU\pers\31223 |
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| 701 | 1 |
_aKiselev _bA. D. _gAleksandr Dmitrievich |
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| 701 | 1 |
_aSoktoev _bB. R. _cGeochemist _cAssociate Professor of the Department of Tomsk Polytechnic University, Candidate of Sciences _f1990- _gBulat Rinchinovich _2stltpush _3(RuTPU)RU\TPU\pers\34950 |
|
| 701 | 1 |
_aBaranovskaya _bN. V. _cgeochemist _cProfessor of Tomsk Polytechnic University, Doctor of biological sciences _f1970- _gNataliya Vladimirovna _2stltpush _3(RuTPU)RU\TPU\pers\31010 |
|
| 712 | 0 | 2 |
_aНациональный исследовательский Томский политехнический университет _bИнженерная школа природных ресурсов _bОтделение геологии _h8083 _2stltpush _3(RuTPU)RU\TPU\col\23542 |
| 801 | 2 |
_aRU _b63413507 _c20230131 _gRCR |
|
| 856 | 4 | _uhttps://doi.org/10.1007/s11270-021-05279-w | |
| 942 | _cCF | ||