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001 665857
005 20231030042017.0
035 _a(RuTPU)RU\TPU\network\37061
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090 _a665857
100 _a20211118a2017 k y0engy50 ba
101 0 _aeng
102 _aUS
135 _adrcn ---uucaa
181 0 _ai
182 0 _ab
200 1 _aSynthesis, Crystal Structure, and Luminescent Properties of Novel Zinc Metal-Organic Frameworks Based on 1,3-Bis(1,2,4-triazol-1-yl)propane
_fE. Yu. Semitut, T. S. Sukhikh, E. Yu. Filatov [et al.]
203 _aText
_celectronic
300 _aTitle screen
320 _a[References: 14 tit.]
330 _aThree new zinc three-dimensional coordination polymers with flexible 1,3-bis(1,2,4-triazol-1-yl)propane ligand were synthesized. The crystal structures of synthesized compounds were determined, and structural peculiarities are discussed. Coordination compounds with composition [Zn(btrp)(bdc)]·nDMF are interpenetrated frameworks, while metal-organic framework (MOF) [Zn3(btrp)(bdc)3]·nDMF is not. Thermal stability and luminescent properties of synthesized compounds have been investigated. The possibility of usage of such compounds as sensitive materials for some aromatic compounds are explored, and it was shown that luminescence of coordination polymers is completely quenched in the presence of nitrobenzene. Sorption properties of synthesized MOFs toward nitrogen, carbon dioxide, and hydrogen were evaluated.
461 _tCrystal Growth & Design
463 _tVol. 17, iss. 10
_v[Р. 5559-5567]
_d2017
610 1 _aэлектронный ресурс
610 1 _aтруды учёных ТПУ
610 1 _aсинтез
610 1 _aкристаллические структуры
610 1 _aлюминесцентные свойства
610 1 _aметаллорганические каркасы
610 1 _aполимеры
610 1 _aцинк
701 1 _aSemitut
_bE. Yu.
_gEvgeny Yurjevich
701 1 _aSukhikh
_bT. S.
_gTaisiya Sergeevna
701 1 _aFilatov
_bE. Yu.
_gEvgeny Yurjevich
701 1 _aAnosova
_bG. A.
_gGalina Aleksandrovna
701 1 _aRyadun
_bA. A.
_gAlexey Andreevich
701 1 _aKovalenko
_bK. A.
_gKonstantin Aleksandrovich
701 1 _aPotapov
_bA. S.
_cChemist
_cProfessor of Tomsk Polytechnic University, Doctor of chemical sciences
_f1981-
_gAndrey Sergeevich
_2stltpush
_3(RuTPU)RU\TPU\pers\33909
712 0 2 _aНациональный исследовательский Томский политехнический университет
_bИнженерная школа энергетики
_bОтделение электроэнергетики и электротехники
_h8022
_2stltpush
_3(RuTPU)RU\TPU\col\23505
801 2 _aRU
_b63413507
_c20211118
_gRCR
856 4 _uhttps://doi.org/10.1021/acs.cgd.7b01133
942 _cCF