| 000 | 03777nlm1a2200565 4500 | ||
|---|---|---|---|
| 001 | 666164 | ||
| 005 | 20231030042028.0 | ||
| 035 | _a(RuTPU)RU\TPU\network\37368 | ||
| 035 | _aRU\TPU\network\36515 | ||
| 090 | _a666164 | ||
| 100 | _a20211209a2021 k y0engy50 ba | ||
| 101 | 0 | _aeng | |
| 102 | _aUS | ||
| 135 | _adrcn ---uucaa | ||
| 181 | 0 | _ai | |
| 182 | 0 | _ab | |
| 200 | 1 |
_aNovel Cyan-Green-Emitting Bi3+-Doped BaScO2F, R+(R=Na, K, Rb) Perovskite Used for Achieving Full-Visible-Spectrum LED Lighting _fCai Mingsheng, Lang Tianchun, Khan Tao [et al.] |
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| 203 |
_aText _celectronic |
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| 300 | _aTitle screen | ||
| 320 | _a[References: 46 tit.] | ||
| 330 | _aCyan-emitting phosphors are important for near-ultraviolet (NUV) light-emitting diodes (LEDs) to gain high-quality white lighting. In the present work, a Bi3+-doped BaScO2F, R+ (R=Na, K, Rb) perovskite, which emits 506 nm cyan-green light under 360 or 415 nm excitation, is obtained via a high-temperature solid-state method for the first time. The obtained perovskite shows improved photoluminescence and thermal stability due to the charge compensation of Na+, K+, and Rb+ co-doping. Its spectral broadening is attributed to two centers Bi (1) and Bi (2), which are caused by the zone-boundary octahedral tilting due to the substitution of Bi3+ for the larger Ba2+. Employing the blend phosphors of Ba0.998ScO2F:0.001Bi3+,0.001K+ and the commercial BAM:Eu2+, YAG:Ce3+, and CaAlSiN3:Eu2+, a full-spectrum white LED device with Ra = 96 and CCT = 4434 K was fabricated with a 360 nm NUV chip. Interestingly, a novel strategy is proposed: the cyan-green Ba0.998ScO2F:0.001Bi3+,0.001K+ and orange Sr3SiO5:Eu2+ phosphors were packaged with a 415 nm NUV chip to produce the white LED with Ra=85 and CCT = 4811 K. | ||
| 333 | _aРежим доступа: по договору с организацией-держателем ресурса | ||
| 461 | _tInorganic Chemistry | ||
| 463 |
_tVol. 60, iss. 20 _v[P. 15519–15528] _d2021 |
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| 610 | 1 | _aэлектронный ресурс | |
| 610 | 1 | _aтруды учёных ТПУ | |
| 610 | 1 | _aизлучения | |
| 610 | 1 | _aсветодиодное освещение | |
| 610 | 1 | _aвидимые спектры | |
| 610 | 1 | _aлюминофоры | |
| 610 | 1 | _aсветодиоды | |
| 610 | 1 | _aбелый свет | |
| 610 | 1 | _aвысокотемпературные методы | |
| 701 | 0 | _aCai Mingsheng | |
| 701 | 0 | _aLang Tianchun | |
| 701 | 0 | _aKhan Tao | |
| 701 | 1 |
_aValiev _bD. T. _cspecialist in the field of material science _cAssociate Professor of Tomsk Polytechnic University, Candidate of Sciences _f1987- _gDamir Talgatovich _2stltpush _3(RuTPU)RU\TPU\pers\33772 |
|
| 701 | 0 | _aFang Shuangqiang | |
| 701 | 0 | _aGuo Chaozhong | |
| 701 | 0 | _aHe Shuangshuang | |
| 701 | 0 | _aPeng Lingling | |
| 701 | 0 | _aCao Shixiu | |
| 701 | 0 | _aBitao Liu | |
| 701 | 0 | _aDu Ling | |
| 701 | 0 |
_aZhong Yang _cspecialist in the field of lightning engineering _cAssociate Professor of Tomsk Polytechnic University, Ph.D _f1990- _2stltpush _3(RuTPU)RU\TPU\pers\39798 |
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| 701 | 1 |
_aPolisadova _bE. F. _cspecialist in the field of lighting engineering _cassociate Professor of Tomsk Polytechnic University, candidate of physico-mathematical Sciences _f1972- _gElena Fyodorovna _2stltpush _3(RuTPU)RU\TPU\pers\33900 |
|
| 712 | 0 | 2 |
_aНациональный исследовательский Томский политехнический университет _bИнженерная школа новых производственных технологий _bОтделение материаловедения _h7871 _2stltpush _3(RuTPU)RU\TPU\col\23508 |
| 801 | 2 |
_aRU _b63413507 _c20211209 _gRCR |
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| 856 | 4 | _uhttps://doi.org/10.1021/acs.inorgchem.1c02150 | |
| 942 | _cCF | ||