| 000 | 02595nlm1a2200385 4500 | ||
|---|---|---|---|
| 001 | 667206 | ||
| 005 | 20231030042103.0 | ||
| 035 | _a(RuTPU)RU\TPU\network\38411 | ||
| 090 | _a667206 | ||
| 100 | _a20220304a2018 k y0engy50 ba | ||
| 101 | 0 | _aeng | |
| 102 | _aGB | ||
| 135 | _adrcn ---uucaa | ||
| 181 | 0 | _ai | |
| 182 | 0 | _ab | |
| 200 | 1 |
_aUltra-fast Suzuki and Heck reactions for the synthesis of styrenes and stilbenes using arenediazonium salts as super-electrophiles _fM. E. Trusova, M. Rodriguez-Zubiri, K. V. Kutonova [et al.] |
|
| 203 |
_aText _celectronic |
||
| 300 | _aTitle screen | ||
| 330 | _aThe super-electrophilic properties of arenediazonium salts have been exploited for achieving ultra-fast palladium-catalyzed coupling reactions with turnover frequencies up to 16 200 h−1. These ultra-fast coupling reactions have been exemplified with the synthesis of prone-to-polymerization styrenes within seconds through Suzuki cross-couplings with potassium vinyltrifluoroborate. Heterocycles and functional groups such as halides were well tolerated. The ambivalent properties of potassium vinyltrifluoroborate also allowed the development of ultra-fast sequential Suzuki-Heck reactions for the preparation of symmetrical and unsymmetrical stilbenes within minutes. | ||
| 333 | _aРежим доступа: по договору с организацией-держателем ресурса | ||
| 461 | _tOrganic Chemistry Frontiers | ||
| 463 |
_tVol. 5, iss. 1 _v[P. 41-45] _d2018 |
||
| 610 | 1 | _aэлектронный ресурс | |
| 610 | 1 | _aтруды учёных ТПУ | |
| 701 | 1 |
_aTrusova _bM. E. _corganic chemist _cAssociate professor of Tomsk Polytechnic University, Candidate of chemical sciences _f1982- _gMarina Evgenievna _2stltpush _3(RuTPU)RU\TPU\pers\31823 |
|
| 701 | 1 |
_aRodriguez-Zubiri _bM. _gMireia |
|
| 701 | 1 |
_aKutonova _bK. V. _gKsenia |
|
| 701 | 1 |
_aJung _bN. _gNicole |
|
| 701 | 1 |
_aBrase _bS. _gStefan |
|
| 701 | 1 |
_aFrancois-Xavier _bF. _gFelpin |
|
| 701 | 1 |
_aPostnikov _bP. S. _corganic chemist _cSenior Lecturer of Tomsk Polytechnic University, Candidate of chemical sciences _f1984- _gPavel Sergeevich _2stltpush _3(RuTPU)RU\TPU\pers\31287 |
|
| 712 | 0 | 2 |
_aНациональный исследовательский Томский политехнический университет _bИсследовательская школа химических и биомедицинских технологий _c(2017- ) _h8120 _2stltpush _3(RuTPU)RU\TPU\col\23537 |
| 801 | 2 |
_aRU _b63413507 _c20220304 _gRCR |
|
| 856 | 4 | _uhttps://doi.org/10.1039/C7QO00750G | |
| 942 | _cCF | ||