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100 _a20220309a2017 k y0engy50 ba
101 0 _aeng
135 _adrcn ---uucaa
181 0 _ai
182 0 _ab
200 1 _aMetals@ZIFs: Catalytic applications and size selective catalysis
_fA. Zanon, F. V. K. Verpoort
203 _aText
_celectronic
300 _aTitle screen
320 _a[References: 151 tit.]
330 _aMetal-organic polyhedra (MOPs) have attracted great interest in the past decade. As a new series of nano-material, MOPs have high outer and inner specific surface areas and are able to be applied in different areas such as catalysis, gas sequestration, drug delivery, molecule sensing, etc. In this review, the focus is made on the design and synthetic strategies approaching edge-bridged tetrahedra MnL6 and face-capped tetrahedra MnL4. Besides the synthesis, structure, and properties of tetrahedral self-assemblies are also considered, while tetrahedra will be compared with other complicated multinuclear constructions. The discussion of how the properties of tetrahedral cages can be altered by varying employed subcomponents is made. Moreover, the multifarious host-guest system and behavior of metal-organic tetrahedral self-assemblies for catalytic applications are addressed in details.
333 _aРежим доступа: по договору с организацией-держателем ресурса
461 _tCoordination Chemistry Reviews
463 _tVol. 353
_v[P. 201–222]
_d2017
610 1 _aэлектронный ресурс
610 1 _aтруды учёных ТПУ
610 1 _aMetals@MOF
610 1 _aNPs
610 1 _aZIFs
610 1 _aselectivity
610 1 _acatalysis
700 1 _aZanon
_bA.
_gAdriano
701 1 _aVerpoort
_bF. V. K.
_cchemist-technologist
_cProfessor of Tomsk Polytechnic University, doctor of chemical Sciences
_f1963-
_gFrensis Valter Kornelius
_2stltpush
_3(RuTPU)RU\TPU\pers\35059
712 0 2 _aНациональный исследовательский Томский политехнический университет
_bИсследовательская школа химических и биомедицинских технологий
_c(2017- )
_h8120
_2stltpush
_3(RuTPU)RU\TPU\col\23537
801 2 _aRU
_b63413507
_c20220309
_gRCR
856 4 _uhttps://doi.org/10.1016/j.ccr.2017.09.030
942 _cCF