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100 _a20220310a2018 k y0engy50 ba
101 0 _aeng
135 _adrcn ---uucaa
181 0 _ai
182 0 _ab
200 1 _aUltra-sensitive, sustainable, and selective electrochemical hydrazine detection by ALD-developed two-dimensional WO3
_fWei Zihan, Hai Zhenyin, M. K. Akbari [et al.]
203 _aText
_celectronic
300 _aTitle screen
320 _a[References: 56 tit.]
330 _aWafer-scale two-dimensional (2D) WO3 films with different thicknesses of 0.78, 1.4, 3.6, and 6.5 nm were fabricated on Au-SiO2/Si substrates using an atomic layer deposition technique. Their surface morphologies and chemical components were examined by field-emission scanning electron microscopy, atomic force microscopy and X-ray photoelectron spectroscopy. Cyclic voltammetry, chronoamperometry and electrochemical impedance spectroscopy were utilized for the analysis of the electrochemical behavior of 2D WO3 films towards hydrazine detection under various conditions. The effect of the thickness of 2D WO3 on the electrochemical performance was also analyzed. Significant improvement in hydrazine sensing capabilities was obtained for monolayer 2D WO3 (0.78 nm), demonstrating a high sensitivity of 1.24 [mu]A μM−1 cm−2, a linear hydrazine concentration detection ranging from 0.2 to 2100 [mu]M, great long-term stability, excellent selectivity and the lowest limit of detection of 0.015 [mu]M reported to date, which provide a great potential method for materials fabrication in the development of high-performance hydrazine detection.
461 _tChemElectroChem
463 _tVol. 5, iss. 2
_v[P. 266-272]
_d2018
610 1 _aэлектронный ресурс
610 1 _aтруды учёных ТПУ
610 1 _aгидразины
610 1 _aповерхности
610 1 _aатомные слои
610 1 _aосаждение
610 1 _aморфология
610 1 _aподложки
701 0 _aWei Zihan
701 0 _aHai Zhenyin
701 1 _aAkbari
_bM. K.
_gMohammad Karbalaei
701 0 _aHu Jie
701 0 _aHyde Lachlan
701 1 _aVerpoort
_bF. V. K.
_cChemical Engineer
_cProfessor of Tomsk Polytechnic University, doctor of chemical Sciences
_f1963-
_gFrensis Valter Kornelius
_2stltpush
_3(RuTPU)RU\TPU\pers\35059
701 1 _aZhuiykov
_bS.
_gSerge
712 0 2 _aНациональный исследовательский Томский политехнический университет
_bИсследовательская школа химических и биомедицинских технологий
_c(2017- )
_h8120
_2stltpush
_3(RuTPU)RU\TPU\col\23537
801 2 _aRU
_b63413507
_c20220310
_gRCR
856 4 _uhttps://doi.org/10.1002/celc.201700968
942 _cCF