| 000 | 03522nlm1a2200493 4500 | ||
|---|---|---|---|
| 001 | 667268 | ||
| 005 | 20231030042105.0 | ||
| 035 | _a(RuTPU)RU\TPU\network\38473 | ||
| 035 | _aRU\TPU\network\38470 | ||
| 090 | _a667268 | ||
| 100 | _a20220311a2022 k y0engy50 ba | ||
| 101 | 0 | _aeng | |
| 102 | _aCH | ||
| 135 | _adrcn ---uucaa | ||
| 181 | 0 | _ai | |
| 182 | 0 | _ab | |
| 200 | 1 |
_aTheoretical and Experimental Research of Hydrogen Solid Solution in Mg and Mg-Al System _fLyu Jinzhe, R. R. Elman, L. A. Svyatkin, V. N. Kudiyarov |
|
| 203 |
_aText _celectronic |
||
| 300 | _aTitle screen | ||
| 320 | _a[References: 49 tit.] | ||
| 330 | _aThe study of hydrogen storage properties of Mg-based thin films is of interest due to their unique composition, interface, crystallinity, and high potential for use in hydrogen-storage systems. Alloying Mg with Al leads to the destabilization of the magnesium hydride reducing the heat of reaction, increases the nucleation rate, and decreases the dehydriding temperature. The purpose of our study is to reveal the role of the aluminum atom addition in hydrogen adsorption and accumulation in the Mg-H solid solution. Ab initio calculations of aluminum and hydrogen binding energies in magnesium were carried out in the framework of density functional theory. Hydrogen distribution and accumulation in Mg and Mg-10%Al thin films were experimentally studied by the method of glow-discharge optical emission spectroscopy and using a hydrogen analyzer, respectively. It was found that a hydrogen distribution gradient is observed in the Mg-10%Al coating, with more hydrogen on the surface and less in the bulk. Moreover, the hydrogen concentration in the Mg-10%Al is lower compared to Mg. This can be explained by the lower hydrogen binding energy in the magnesium-aluminum system compared with pure magnesium. | ||
| 338 |
_bРоссийский научный фонд _d19-19-00192 |
||
| 461 | _tMaterials | ||
| 463 |
_tVol. 15, iss. 5 _v[1667, 13 p.] _d2022 |
||
| 610 | 1 | _aэлектронный ресурс | |
| 610 | 1 | _aтруды учёных ТПУ | |
| 610 | 1 | _amagnesium | |
| 610 | 1 | _aaluminum | |
| 610 | 1 | _athin film | |
| 610 | 1 | _ahydrogen | |
| 610 | 1 | _afirst-principle calculations | |
| 610 | 1 | _aмагний | |
| 610 | 1 | _aалюминий | |
| 610 | 1 | _aтонкие пленки | |
| 610 | 1 | _aводород | |
| 701 | 0 |
_aLyu Jinzhe _cphysicist _cengineer of Tomsk Polytechnic University _f1993- _2stltpush _3(RuTPU)RU\TPU\pers\45439 |
|
| 701 | 1 |
_aElman _bR. R. _cphysicist _cEngineer of Tomsk Polytechnic University _f1997- _gRoman Romanovich _2stltpush _3(RuTPU)RU\TPU\pers\47123 |
|
| 701 | 1 |
_aSvyatkin _bL. A. _cphysicist _cAssociate Professor of Tomsk Polytechnic University, Candidate of Physical and Mathematical Sciences _f1988- _gLeonid Aleksandrovich _2stltpush _3(RuTPU)RU\TPU\pers\34216 |
|
| 701 | 1 |
_aKudiyarov _bV. N. _cphysicist _cAssociate Professor of Tomsk Polytechnic University, Candidate of Technical Sciences _f1990- _gVictor Nikolaevich _2stltpush _3(RuTPU)RU\TPU\pers\30836 |
|
| 712 | 0 | 2 |
_aНациональный исследовательский Томский политехнический университет _bИнженерная школа ядерных технологий _bОтделение экспериментальной физики _h7865 _2stltpush _3(RuTPU)RU\TPU\col\23549 |
| 801 | 2 |
_aRU _b63413507 _c20220513 _gRCR |
|
| 856 | 4 | _uhttp://earchive.tpu.ru/handle/11683/70739 | |
| 856 | 4 | _uhttps://doi.org/10.3390/ma15051667 | |
| 942 | _cCF | ||