| 000 | 02665nlm1a2200421 4500 | ||
|---|---|---|---|
| 001 | 667325 | ||
| 005 | 20231030042107.0 | ||
| 035 | _a(RuTPU)RU\TPU\network\38530 | ||
| 035 | _aRU\TPU\network\18720 | ||
| 090 | _a667325 | ||
| 100 | _a20220315a2015 k y0engy50 ba | ||
| 101 | 0 | _aeng | |
| 135 | _adrgn ---uucaa | ||
| 181 | 0 | _ai | |
| 182 | 0 | _ab | |
| 200 | 1 |
_aInvestigations into the Speciationof Inorganic Arsenicin Weakly Alkaline Medium by Voltammetry _fE. A. Zakharova, G. N. Noskova, M. L. Moskaleva [et al.] |
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| 203 |
_aText _celectronic |
||
| 300 | _aTitle screen | ||
| 320 | _a[References: 42 tit.] | ||
| 330 | _aThe speciation of inorganic forms of arsenic was studied using anodic stripping voltammetry (ASV) at a gold microelectrode in conjunction with photoreduction of As(V). Sodium sulfite (0.1 M) and ammonium buffer (pH≥9.5) were selected as both background electrolyte and photo-reductive reagent. Oxygen was removed by radical chain reactions with sulfite. The proposed speciation method was validated for mixtures of arsenic As(III/V) at concentrations up to 1 mg L−1. The calculated LOD of As(III/V) was 0.06 µg L−1 (3σ, tdep 40 s). Any interference from nitrate anions present at up to millimolar concentration was minimized by their photoreduction. | ||
| 333 | _aРежим доступа: по договору с организацией-держателем ресурса | ||
| 461 | _tElectroanalysis | ||
| 463 |
_tVol. 27, iss. 3 _v[P. 890–901] _d2015 |
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| 610 | 1 | _aэлектронный ресурс | |
| 610 | 1 | _aтруды учёных ТПУ | |
| 610 | 1 | _aмышьяк | |
| 610 | 1 | _aвольтамперометрия | |
| 610 | 1 | _aфотовосстановление | |
| 610 | 1 | _aнеорганические формы | |
| 701 | 1 |
_aZakharova _bE. A. _cchemist _csenior research fellow at the Tomsk Polytechnic University, candidate of chemical Sciences _f1938- _gElsa Arminana _2stltpush _3(RuTPU)RU\TPU\pers\33332 |
|
| 701 | 1 |
_aNoskova _bG. N. _gGalina Nikolaevna |
|
| 701 | 1 |
_aMoskaleva _bM. L. _gMarina Leonidovna |
|
| 701 | 1 |
_aElesova _bE. E. _gElena Evgenjevna |
|
| 701 | 1 |
_aWildgoose _bG. G. _gGregory |
|
| 712 | 0 | 2 |
_aНациональный исследовательский Томский политехнический университет (ТПУ) _bИнститут природных ресурсов (ИПР) _bКафедра гидрогеологии, инженерной геологии и гидрогеоэкологии (ГИГЭ) _h100 _2stltpush _3(RuTPU)RU\TPU\col\18664 |
| 801 | 2 |
_aRU _b63413507 _c20220315 _gRCR |
|
| 856 | 4 | _uhttps://doi.org/10.1002/elan.201500034 | |
| 942 | _cCF | ||