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101 0 _aeng
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181 0 _ai
182 0 _ab
200 1 _aBlack Swan in Phase Transfer Catalysis: Influence of Mixing Mode on the Stereoselectivity of Glycosylation
_fI. V. Myachin, Z. Mamirgova, E. V. Stepanova [et al.]
203 _aText
_celectronic
300 _aTitle screen
320 _a[References: 44 tit.]
330 _aThe influence of mixing mode on the outcome of the glycosylation under phase transfer conditions (batch vs flow) is found to be more complicated than it is generally assumed. A change in the way reagents are mixed leads not only to the enhanced mass transfer and consequently higher yield but also to a change in reaction mechanism.
338 _bРоссийский научный фонд
_d21-73-20164
461 _tEuropean Journal of Organic Chemistry
463 _tVol. 2022, iss. 14
_v[e202101377, 9 p.]
_d2022
610 1 _aэлектронный ресурс
610 1 _aтруды учёных ТПУ
610 1 _aстереоселективность
610 1 _aгликозилирование
610 1 _aсмешение
610 1 _aреагенты
610 1 _aмассообмен
610 1 _aкатализ
610 1 _aфазовый перенос
701 1 _aMyachin
_bI. V.
_gIljya
701 1 _aMamirgova
_bZ.
_gZarina
701 1 _aStepanova
_bE. V.
_cchemist
_cAssociate Professor of Tomsk Polytechnic University, Candidate of Chemical Sciences
_f1988-
_gElena Vladimirovna
_2stltpush
_3(RuTPU)RU\TPU\pers\34245
701 1 _aZinin
_bA. I.
_gAleksandr Ivanovich
701 1 _aChizhov
_bA. O.
_gAleksandr Olegovich
701 1 _aKononov
_bL. O.
_gLeonid Olegovich
712 0 2 _aНациональный исследовательский Томский политехнический университет
_bИсследовательская школа химических и биомедицинских технологий (ИШХБМТ)
_c(2017- )
_h8120
_2stltpush
_3(RuTPU)RU\TPU\col\23537
801 2 _aRU
_b63413507
_c20220516
_gRCR
856 4 _uhttps://doi.org/10.1002/ejoc.202101377
942 _cCF