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|---|---|---|---|
| 001 | 667960 | ||
| 005 | 20231030042132.0 | ||
| 035 | _a(RuTPU)RU\TPU\network\39171 | ||
| 035 | _aRU\TPU\network\35384 | ||
| 090 | _a667960 | ||
| 100 | _a20220518a2022 k y0engy50 ba | ||
| 101 | 0 | _aeng | |
| 102 | _aNL | ||
| 135 | _adrcn ---uucaa | ||
| 181 | 0 | _ai | |
| 182 | 0 | _ab | |
| 200 | 1 |
_aPolymer waste surgical masks decorated by superhydrophobic metal-organic frameworks towards oil spills clean-up _fO. A. Guselnikova, O. V. Semyonov, M. V. Kirgina [et al.] |
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| 203 |
_aText _celectronic |
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| 300 | _aTitle screen | ||
| 320 | _a[References: 51 tit.] | ||
| 330 | _aThe pandemic of COVID-19 led to drastic increase in the production of polymer medical disposals, where surgical masks and hospital sheets, made from polypropylene (PP), bring large carbon footprints after burning as a dominant recycling scenario. Here, we offer an alternative strategy of functional recycling for medical disposals to prolong the life cycle of waste PP to oil spill sorbent. Simple deposition of the superhydrophobic fluorine-free metal-azolate framework (MAF-6) leads to the preparation of advanced materials PP-MAF6 for oil spill clean-up. Optimized procedures allow obtaining superhydrophobic oleophilic fabric with mechanical robustness and UV resistance. The prepared PP-MAF6 shows high adsorption capacity towards a wide range of oils in 4-10 pH range, including straight-run diesel fuel (> 25000 mg/g) with the > 99.9% oil removal efficiency. To complement adsorption performance, we scaled up the preparation procedure of PP-MAF6 to 65 cm2. Finally, enlarged samples were capable to fully clean up the simulated sample containing solid contaminants (total organic carbon content <0.0018 g/L; Zn, Fe concentration < 0.3 mg/L). The PP-MAF6 shows great potential in accident elimination of oil spills containing solid components in the contaminated water in a fast manner. The strategy of functional polymer recycling is promising for treating practical oil spills. | ||
| 333 | _aРежим доступа: по договору с организацией-держателем ресурса | ||
| 461 | _tJournal of Environmental Chemical Engineering | ||
| 463 |
_tVol. 10, iss. 2 _v[107105, 11 p.] _d2022 |
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| 610 | 1 | _aэлектронный ресурс | |
| 610 | 1 | _aтруды учёных ТПУ | |
| 610 | 1 | _apolymer recycling | |
| 610 | 1 | _ametal organic framework | |
| 610 | 1 | _aoil spill | |
| 610 | 1 | _aoil spill | |
| 610 | 1 | _asuperhydrophobicity | |
| 610 | 1 | _aрециклинг | |
| 610 | 1 | _aполимеры | |
| 610 | 1 | _aорганические каркасы | |
| 610 | 1 | _aразливы нефти | |
| 610 | 1 | _aполимерные отходы | |
| 701 | 1 |
_aGuselnikova _bO. A. _cchemist _cengineer of Tomsk Polytechnic University _f1992- _gOlga Andreevna _2stltpush _3(RuTPU)RU\TPU\pers\34478 |
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| 701 | 1 |
_aSemyonov _bO. V. _cprocess chemist _cJunior Researcher, Tomsk Polytechnic University _f1993- _gOleg Vladimirovich _2stltpush _3(RuTPU)RU\TPU\pers\45298 |
|
| 701 | 1 |
_aKirgina _bM. V. _cChemical Engineer _cAssociate Professor of Tomsk Polytechnic University, Candidate of Technical Sciences _f1988- _gMariya Vladimirovna _2stltpush _3(RuTPU)RU\TPU\pers\31994 |
|
| 701 | 1 |
_aIvanov _bA. A. _cspecialist in the field of Electrophysics _cengineer of Tomsk Polytechnic University _f1990- _gAleksey Alekseevich _2stltpush _3(RuTPU)RU\TPU\pers\35679 |
|
| 701 | 1 |
_aZinoviev _bA. L. _cChemist _cJunior Researcher Tomsk Polytechnic University _f1992- _gAlexey Leonidovich _2stltpush _3(RuTPU)RU\TPU\pers\42081 |
|
| 701 | 1 |
_aPostnikov _bP. S. _corganic chemist _cAssociate Professor of Tomsk Polytechnic University, Candidate of chemical sciences _f1984- _gPavel Sergeevich _2stltpush _3(RuTPU)RU\TPU\pers\31287 |
|
| 712 | 0 | 2 |
_aНациональный исследовательский Томский политехнический университет _bИнженерная школа энергетики _bНаучно-образовательный центр И. Н. Бутакова (НОЦ И. Н. Бутакова) _h8025 _2stltpush _3(RuTPU)RU\TPU\col\23504 |
| 801 | 2 |
_aRU _b63413507 _c20220518 _gRCR |
|
| 856 | 4 | _uhttps://doi.org/10.1016/j.jece.2021.107105 | |
| 942 | _cCF | ||