| 000 | 04080nlm1a2200457 4500 | ||
|---|---|---|---|
| 001 | 668060 | ||
| 005 | 20231030042136.0 | ||
| 035 | _a(RuTPU)RU\TPU\network\39284 | ||
| 035 | _aRU\TPU\network\35049 | ||
| 090 | _a668060 | ||
| 100 | _a20220602a2022 k y0engy50 ba | ||
| 101 | 0 | _aeng | |
| 135 | _adrcn ---uucaa | ||
| 181 | 0 | _ai | |
| 182 | 0 | _ab | |
| 200 | 1 |
_aMagnetoelectric coupling studies in lead-free multiferroic (Ba0.85Ca0.15)(Zr0.1Ti0.9)O3−(Ni0.7Zn0.3)Fe2O4 ceramic composites _fI. Coondoo, J. Vidal, I. Bdikin [et al.] |
|
| 203 |
_aText _celectronic |
||
| 300 | _aTitle screen | ||
| 320 | _a[References: 81 tit.] | ||
| 330 | _aLead-free multiferroic 3-0 type particulate composites with a composition (1−x)(Ba0.85Ca0.15Zr0.1Ti0.9O3) - x(Ni0.7Zn0.3Fe2O4) [(1−x)BCZT - xNZFO with 0 ≤ x ≤ 100 at%] were prepared using solid state reaction method. Structural and microstructural analysis using XRD, FESEM and Raman techniques confirmed the phase formation of the ferroelectric (BCZT) and magnetostrictive (NZFO) phases without any detectable presence of impurity phases. Rietveld refinement of the XRD data revealed a tetragonal (P4mm) and a cubic structure (Fd3‾m) for the BCZT and NZFO phases, respectively. Elemental compositions of the constituent phases were assessed by EDS and XPS analyses. Electrical, magnetic, and magnetoelectric (ME) measurements were performed. The composites exhibit typical well-saturated magnetic hysteresis (M−H) loops at room temperature, having very low coercive field (HC) values, indicating their soft ferromagnetic behavior. Various parameters extracted from the M−H curves including HC, magneto-crystalline anisotropy, squareness, and magnetization were found to depend on x. Frequency dependence of capacitance and admittance exhibited a resonance behavior corresponding to the radial mode of the electromechanical resonance (EMR). ME coefficients were studied in both longitudinal (αE33) and transverse (αE31) modes. The highest coupling coefficients, αE31 ∼14.5 mV/Oe.cm and αE33 ∼13 mV/Oe.cm were obtained for composite with 50 at% NZF at off-resonance frequency of 1 kHz. At the EMR frequency of 314 kHz, the αE31 value in 0.5BCZT-0.5NZFO composite enhanced enormously to ∼5.5 V/Oe.cm. The studies conclude that x = 0.5 is an optimum atomic fraction of NZFO in the particulate composite for maximum ME coupling. | ||
| 333 | _aРежим доступа: по договору с организацией-держателем ресурса | ||
| 461 | _tCeramics International | ||
| 463 |
_tVol. 48, iss. 17 _v[P. 24439-24453] _d2022 |
||
| 610 | 1 | _aэлектронный ресурс | |
| 610 | 1 | _aтруды учёных ТПУ | |
| 610 | 1 | _amultiferroic | |
| 610 | 1 | _amagnetoelectric coupling | |
| 610 | 1 | _aBCZT | |
| 610 | 1 | _aNZFO | |
| 610 | 1 | _acomposite | |
| 610 | 1 | _aмультиферроики | |
| 610 | 1 | _aкомпозиты | |
| 701 | 1 |
_aCoondoo _bI. _gIndrani |
|
| 701 | 1 |
_aVidal _bJ. _gJoao |
|
| 701 | 1 |
_aBdikin _bI. _gIgor |
|
| 701 | 1 |
_aSurmenev _bR. A. _cphysicist _cAssociate Professor of Tomsk Polytechnic University, Senior researcher, Candidate of physical and mathematical sciences _f1982- _gRoman Anatolievich _2stltpush _3(RuTPU)RU\TPU\pers\31885 |
|
| 701 | 1 |
_aKholkin _bA. L. _cphysicist _cDirector of the International Research Center for PMEM of the Tomsk Polytechnic University, Candidate of Physical and Mathematical Sciences _f1954- _gAndrei Leonidovich _2stltpush _3(RuTPU)RU\TPU\pers\47207 |
|
| 712 | 0 | 2 |
_aНациональный исследовательский Томский политехнический университет _bИсследовательская школа химических и биомедицинских технологий _bНаучно-исследовательский центр "Физическое материаловедение и композитные материалы" _h8209 _2stltpush _3(RuTPU)RU\TPU\col\24957 |
| 801 | 2 |
_aRU _b63413507 _c20220928 _gRCR |
|
| 856 | 4 | _uhttps://doi.org/10.1016/j.ceramint.2022.05.052 | |
| 942 | _cCF | ||