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100 _a20220706a2022 k y0engy50 ba
101 0 _aeng
135 _adrcn ---uucaa
181 0 _ai
182 0 _ab
200 1 _aIn Vitro Biodegradation of a-C:H:SiOx Films on Ti-6Al-4V Alloy
_fA. S. Grenaderov, A. Solovyev, K. V. Oskomov [et al.]
203 _aText
_celectronic
300 _aTitle screen
320 _a[References: 55 tit.]
330 _aThis paper focuses mainly on the in vitro study of a five-week biodegradation of a-C:H:SiOx films of different thickness, obtained by plasma-assisted chemical vapor deposition onto Ti-6Al-4V alloy substrate using its pulsed bipolar biasing. In vitro immersion of a-C:H:SiOx films in a solution of 0.9% NaCl was used. It is shown how the a-C:H:SiOx film thickness (0.5-3 µm) affects the surface morphology, adhesive strength, and Na+ and Cl− precipitation on the film surface from the NaCl solution. With increasing film thickness, the roughness indices are reducing a little. The adhesive strength of the a-C:H:SiOx films to metal substrate corresponds to quality HF1 (0.5 µm in thickness) and HF2-HF3 (1.5-3 µm in thickness) of the Rockwell hardness test (VDI 3198) that defines strong interfacial adhesion and is usually applied in practice. The morphometric analysis of the film surface shows that on a-C:H:SiOx-coated Ti-6Al-4V alloy surface, the area occupied by the grains of sodium chloride is lower than on the uncoated surface. The reduction in the ion precipitation from 0.9% NaCl onto the film surface depended on the elemental composition of the surface layer conditioned by the thickness growth of the a-C:H:SiOx film. Based on the results of energy dispersive X-ray spectroscopy, the multiple regression equations are suggested to explain the effect of the elemental composition of the a-C:H:SiOx film on the decreased Na+ and Cl− precipitation. As a result, the a-C:H:SiOx films successfully combine good adhesion strength and rare ion precipitation and thus are rather promising for medical applications on cardiovascular stents and/or friction parts of heart pumps.
461 _tMaterials
463 _tVol. 15, iss. 12
_v[4239, 17 p.]
_d2022
610 1 _aэлектронный ресурс
610 1 _aтруды учёных ТПУ
610 1 _adiamond-like nanocomposite
610 1 _aa-C:H:SiOx film
610 1 _aadhesion
610 1 _afive-week biodegradation
610 1 _a0.9% NaCl solution
610 1 _aалмазоподобные соединения
610 1 _aнанокомпозиты
610 1 _aадгезия
701 1 _aGrenaderov
_bA. S.
_gAleksandr Sergeevich
701 1 _aSolovyev
_bA.
_gAndrey
701 1 _aOskomov
_bK. V.
_gKonstantin Vladimirovich
701 1 _aPorokhova
_bE.
_gEkaterina
701 1 _aBrazovsky (Brazovskii)
_bK. S.
_cspecialist in the field of electronics
_ccandidate of medical Sciences, associate Professor Tomsk Polytechnic University
_f1971-
_gKonstantin Stanislavovich
_2stltpush
_3(RuTPU)RU\TPU\pers\36870
701 1 _aGorokhova
_bA. V.
_gAnna Viktorovna
701 1 _aNasibov
_bT.
_gTemur
701 1 _aLitvinova
_bL.
_gLarisa
701 1 _aKhlusov
_bI. A.
_cbiophysicist
_cProfessor of Tomsk Polytechnic University, doctor of medical Sciences
_f1963-
_gIgor Albertovich
_2stltpush
_3(RuTPU)RU\TPU\pers\34907
712 0 2 _aНациональный исследовательский Томский политехнический университет
_bИсследовательская школа химических и биомедицинских технологий
_c(2017- )
_h8120
_2stltpush
_3(RuTPU)RU\TPU\col\23537
801 2 _aRU
_b63413507
_c20220706
_gRCR
856 4 _uhttps://doi.org/10.3390/ma15124239
942 _cCF