000 03555nlm1a2200445 4500
001 668659
005 20231030042155.0
035 _a(RuTPU)RU\TPU\network\39896
035 _aRU\TPU\network\39099
090 _a668659
100 _a20230116a2022 k y0engy50 ba
101 0 _aeng
102 _aNL
135 _adrcn ---uucaa
181 0 _ai
182 0 _ab
200 1 _aUnsteady state simulation of gasoline fraction pyrolysis
_fA. A. Bunaev, I. M. Dolganov, I. O. Dolganova
203 _aText
_celectronic
300 _aTitle screen
330 _aPyrolysis of various hydrocarbon feedstock is one of the key processes for production of monomers for polymer industry. During this process mixture of hydrocarbons is heated at high temperatures and in the absence of oxygen in furnace coil. However, coke settles on the inner walls of the coil due to side reactions of polymerization and consecutive polycondensation. This phenomenon decreases efficiency of process, thus, making it unstable. Therefore, existing stationary models might not be suitable for simulation of the process as they do not usually take into account influence of coke formations on kinetic, hydrodynamic or thermal aspects of pyrolysis. In this paper, development of unsteady-state model is presented as incremental improvement towards the solution of process optimization and forecasting of its performance. Thus, the model provides ability to understand deeper the influence of operating parameters on the coke formation process. The model allows to simulate coke deposition along the coil through intergeneration cycle, considering composition of provided feedstock. Dependencies of target products yields and coke layer growth rate on such operating parameters as inlet pressure, temperature and feedstock mass flow rate were determined. The inlet pressure varied from 0.3 to 0.75 MPa, the temperature varied from 780 to 850 °C and the flow rate – from 3600 to 5000 kg/h.
333 _aРежим доступа: по договору с организацией-держателем ресурса
461 _tSouth African Journal of Chemical Engineering
463 _tVol. 42
_v[P. 146-155]
_d2022
610 1 _aэлектронный ресурс
610 1 _aтруды учёных ТПУ
610 1 _apyrolysis
610 1 _ahydrocarbon feedstock
610 1 _aunsteady-state
610 1 _amathematical model
610 1 _aпиролиз
610 1 _aуглеводородное сырье
610 1 _aнестационарные состояния
610 1 _aматематические модели
700 1 _aBunaev
_bA. A.
_cchemist
_cengineer of Tomsk Polytechnic University
_f1996-
_gAyur Alekseevich
_2stltpush
_3(RuTPU)RU\TPU\pers\47027
701 1 _aDolganov
_bI. M.
_cChemical Engineer
_cEngineer of Tomsk Polytechnic University
_f1987-
_gIgor Mikhailovich
_2stltpush
_3(RuTPU)RU\TPU\pers\32216
701 1 _aDolganova
_bI. O.
_cchemist
_cAssociate Scientist of Tomsk Polytechnic University, postgraduate student, candidate of technical Sciences
_f1988-
_gIrena Olegovna
_2stltpush
_3(RuTPU)RU\TPU\pers\31271
712 0 2 _aНациональный исследовательский Томский политехнический университет
_bИнженерная школа природных ресурсов
_bОтделение химической инженерии
_h8085
_2stltpush
_3(RuTPU)RU\TPU\col\23513
801 2 _aRU
_b63413507
_c20230116
_gRCR
856 4 _uhttps://doi.org/10.1016/j.sajce.2022.08.007
942 _cCF