| 000 | 03070nlm1a2200469 4500 | ||
|---|---|---|---|
| 001 | 668881 | ||
| 005 | 20231030042203.0 | ||
| 035 | _a(RuTPU)RU\TPU\network\40118 | ||
| 035 | _aRU\TPU\network\40116 | ||
| 090 | _a668881 | ||
| 100 | _a20230131a2022 k y0engy50 ba | ||
| 101 | 0 | _aeng | |
| 102 | _aCH | ||
| 135 | _adrcn ---uucaa | ||
| 181 | 0 | _ai | |
| 182 | 0 | _ab | |
| 200 | 1 |
_aTandem Reactions Based on the Cyclization of Carbon Dioxide and Propargylic Alcohols: Derivative Applications of a-Alkylidene Carbonates _fJiang Bowen, Yan Xiangyu, Xu Yong [et al.] |
|
| 203 |
_aText _celectronic |
||
| 300 | _aTitle screen | ||
| 320 | _a[References: 139 tit.] | ||
| 330 | _aAs a well-known greenhouse gas, carbon dioxide (CO2) has attracted increasing levels of attention in areas of energy, environment, climate, etc. Notably, CO2 is an abundant, nonflammable, and renewable C1 feedstock in view of chemistry. Therefore, the transformation of CO2 into organic compounds is an extremely attractive research topic in modern green and sustainable chemistry. Among the numerous CO2 utilization methods, carboxylative cycloaddition of CO2 into propargylic alcohols is an ideal route due to the corresponding products, a-alkylidene cyclic carbonates, which are a series of highly functionalized compounds that supply numerous potential methods for the construction of various synthetically and biologically valuable agents. This cyclization reaction has been intensively studied and systematically summarized, in the past years. Therefore, attention has been gradually transferred to produce more derivative compounds. Herein, the tandem reactions of this cyclization with hydration, amination, alcoholysis, and isomerization to synthesize a-hydroxyl ketones, oxazolidinones, carbamates, unsymmetrical carbonates, tetronic acids, ethylene carbonates, etc. were systematically reviewed. | ||
| 461 | _tCatalysts | ||
| 463 |
_tVol. 12 iss. 1 _v[73, 35 p.] _d2022 |
||
| 610 | 1 | _aэлектронный ресурс | |
| 610 | 1 | _aтруды учёных ТПУ | |
| 610 | 1 | _acarbon dioxide transformation | |
| 610 | 1 | _atandem reactions | |
| 610 | 1 | _apropargylic alcohols | |
| 610 | 1 | _aa-alkylidene carbonates | |
| 610 | 1 | _agreen synthesis | |
| 701 | 0 | _aJiang Bowen | |
| 701 | 0 | _aYan Xiangyu | |
| 701 | 0 | _aXu Yong | |
| 701 | 1 |
_aLikhanova _bN. _gNatalya |
|
| 701 | 1 |
_aVelazquez _bH. D. _gHeriberto Diaz |
|
| 701 | 0 | _aGong Yanyan | |
| 701 | 0 | _aYuan Ye | |
| 701 | 1 |
_aVerpoort _bF. V. K. _cChemical Engineer _cProfessor of Tomsk Polytechnic University, doctor of chemical Sciences _f1963- _gFrensis Valter Kornelius _2stltpush _3(RuTPU)RU\TPU\pers\35059 |
|
| 712 | 0 | 2 |
_aНациональный исследовательский Томский политехнический университет _bИсследовательская школа химических и биомедицинских технологий _c(2017- ) _h8120 _2stltpush _3(RuTPU)RU\TPU\col\23537 |
| 801 | 2 |
_aRU _b63413507 _c20230131 _gRCR |
|
| 856 | 4 | _uhttps://doi.org/10.3390/catal12010073 | |
| 942 | _cCF | ||