| 000 | 03070nlm1a2200457 4500 | ||
|---|---|---|---|
| 001 | 669060 | ||
| 005 | 20231030042209.0 | ||
| 035 | _a(RuTPU)RU\TPU\network\40297 | ||
| 035 | _aRU\TPU\network\37960 | ||
| 090 | _a669060 | ||
| 100 | _a20230209a2022 k y0engy50 ba | ||
| 101 | 0 | _aeng | |
| 102 | _aNL | ||
| 135 | _adrcn ---uucaa | ||
| 181 | 0 | _ai | |
| 182 | 0 | _ab | |
| 200 | 1 |
_aN-functionalized hierarchical carbon composite derived from ZIF-67 and carbon foam for efficient overall water splitting _fWang Jichao, Chaemchuen Somboon, Chen Cheng [et al.] |
|
| 203 |
_aText _celectronic |
||
| 300 | _aTitle screen | ||
| 320 | _a[References: 52 tit.] | ||
| 330 | _aAn efficient and facile approach to synthesize a bi-functional electrocatalyst via combining carbon foam with cobalt-centered zeolitic imidazolate framework (ZIF-67) is reported. The carbon foam was synthesized via dehydration of sugar utilizing zinc nitrate, forming Co3ZnC in the carbon matrix. To obtain Co hybridized and Co particles covered with carbon nanotubes embedded in a carbon matrix (Co-Zn-CNTs), physical mixing of both defines the critical point after pyrolysis. Higher content of N-related species and transition metal species in polyvalent states and well-grown multi-wall carbon nanotubes for charge transfer are achieved after the pyrolysis process. The obtained Co-Zn-CNTs catalyst was employed as cathode and anode for overall water splitting (HER and OER) and showed excellent performances. This development offers a low-cost and straightforward strategy to synthesize catalyst material for large-scale fuel cells and water splitting technologies. This development affords a precise method for effectively improving the electrocatalyst performance derived from the ZIF-67 precursor. | ||
| 333 | _aРежим доступа: по договору с организацией-держателем ресурса | ||
| 461 | _tJournal of Industrial and Engineering Chemistry | ||
| 463 |
_tVol. 105 _v[P. 222-230] _d2022 |
||
| 610 | 1 | _aэлектронный ресурс | |
| 610 | 1 | _aтруды учёных ТПУ | |
| 610 | 1 | _azeolitic imidazolate frameworks | |
| 610 | 1 | _acarbon foam | |
| 610 | 1 | _abimetallic electrocatalyst | |
| 610 | 1 | _acarbon nanotubes | |
| 610 | 1 | _awater splitting | |
| 701 | 0 | _aWang Jichao | |
| 701 | 0 | _aChaemchuen Somboon | |
| 701 | 0 | _aChen Cheng | |
| 701 | 1 |
_aHeynderickx _bPh. M. _gPhilippe |
|
| 701 | 0 | _aSoumyajit Roy | |
| 701 | 1 |
_aVerpoort _bF. V. K. _cChemical Engineer _cProfessor of Tomsk Polytechnic University, doctor of chemical Sciences _f1963- _gFrensis Valter Kornelius _2stltpush _3(RuTPU)RU\TPU\pers\35059 |
|
| 712 | 0 | 2 |
_aНациональный исследовательский Томский политехнический университет _bИсследовательская школа химических и биомедицинских технологий _c(2017- ) _h8120 _2stltpush _3(RuTPU)RU\TPU\col\23537 |
| 801 | 2 |
_aRU _b63413507 _c20230209 _gRCR |
|
| 856 | 4 | _uhttps://doi.org/10.1016/j.jiec.2021.09.024 | |
| 942 | _cCF | ||