| 000 | 03101nam0a2200373 4500 | ||
|---|---|---|---|
| 001 | 669225 | ||
| 005 | 20231030042215.0 | ||
| 035 | _a(RuTPU)RU\TPU\network\40465 | ||
| 035 | _aRU\TPU\network\40464 | ||
| 090 | _a669225 | ||
| 100 | _a20230302a2013 k y0engy50 ba | ||
| 101 | 0 | _aeng | |
| 102 | _aNL | ||
| 105 | _ay z 100zy | ||
| 135 | _adrcn ---uucaa | ||
| 181 | 0 | _ai | |
| 182 | 0 | _ab | |
| 200 | 1 |
_aDirect Synthesis of Sulphide Multifunctional Catalysts for Hydrogenolysis _fT. A. Fedushchak, A. S. Akimov, M. A. Morozov [et al.] |
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| 203 |
_aText _celectronic |
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| 320 | _a[References: 2 tit.] | ||
| 330 | _aNew technologies for production of bulk catalysts require that the available catalyst systems be essentially improved. The advantage of bulk catalysts on inflicted catalysts is in the freedom to vary the active component concentration in a wide range of values. Bulk sulfide catalysts are usually prepared by co-precipitation, mechanical activation of precursor salts and micelar synthesis of solid sulfide particles. Furthermore Мо/W and 3d-metal oxides are always formed as intermediates. According to the literature attempts to obtain highly active catalyst for hydrogenolysis from macrocrystalline MoS2 failed to be success. In this paper we present the results on direct solid-phase synthesis of sulfide catalysts based on different MoS2 (MoS2, obtained by self-propagating high-temperature synthesis from electroexplosive Мо nano-powder and elemental S, Fig.1а, and commercial macrocrystalline product, Fig.1b), as well promoters taken as electro-explosive nano-sized Ni and Со powders or micron-sized powders. Nano-fiber γ-AlOOH (Fig.1d), obtained from electro-explosive nano-powder AlN and detonation nano-diamonds were used as binders. Solid-phase synthesis of the catalytic systems was carried out via mechanical activation of MoS2 and promoters at dispersion during 4 - 24 hours. | ||
| 463 |
_tMolecular Aspects of Catalysis by Sulfides (MACS) _oVIth International Symposium, 12-16 May, 2013 Satillieu, France _v[1 p.] _d2013 |
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| 610 | 1 | _aэлектронный ресурс | |
| 610 | 1 | _aтруды учёных ТПУ | |
| 701 | 1 |
_aFedushchak _bT. A. _gTaisiya Alexandrovna |
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| 701 | 1 |
_aAkimov _bA. S. _gAkim Semenovich |
|
| 701 | 1 |
_aMorozov _bM. A. _gMaxim Alexandrovich |
|
| 701 | 1 |
_aVosmerikov _bA. V. |
|
| 701 | 1 |
_aUimin _bM. A. _gMikhail Alexandrovich |
|
| 701 | 1 |
_aZhuravkov _bS. P. _cchemist _cLeading Researcher, Associate Professor of Tomsk Polytechnic University, Candidate of Chemical Sciences _f1961- _gSergey Petrovich _2stltpush _3(RuTPU)RU\TPU\pers\31297 |
|
| 712 | 0 | 2 |
_aНациональный исследовательский Томский политехнический университет (ТПУ) _bИнститут природных ресурсов (ИПР) _bКафедра химической технологии топлива и химической кибернетики (ХТТ) _h105 _2stltpush _3(RuTPU)RU\TPU\col\18665 |
| 801 | 2 |
_aRU _b63413507 _c20230302 _gRCR |
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| 856 | 4 | _uhttps://www.elibrary.ru/item.asp?id=50301429 | |
| 942 | _cBK | ||