| 000 | 03705nlm1a2200409 4500 | ||
|---|---|---|---|
| 001 | 669581 | ||
| 005 | 20231030042227.0 | ||
| 035 | _a(RuTPU)RU\TPU\network\40833 | ||
| 035 | _aRU\TPU\network\39362 | ||
| 090 | _a669581 | ||
| 100 | _a20230628a2022 k y0engy50 ba | ||
| 101 | 0 | _aeng | |
| 102 | _aUS | ||
| 135 | _adrcn ---uucaa | ||
| 181 | 0 | _ai | |
| 182 | 0 | _ab | |
| 200 | 1 |
_aPolymorph-Dependent Phosphorescence of Cyclometalated Platinum(II) Complexes and Its Relation to Non-covalent Interactions _fE. V. Sokolova, M. A. Kinzhalov, A. S. Smirnov [et al.] |
|
| 203 |
_aText _celectronic |
||
| 300 | _aTitle screen | ||
| 320 | _a[References: 76 tit.] | ||
| 330 | _aCyclometalated platinum(II) complexes [Pt(ppy)Cl(CNAr)] (ppy = 2-phenylpyridinato-C2,N; Ar = C6H4-2-I 1, C6H4-4-I 2, C6H3-2-F-4-I 3, and C6H3-2,4-I24) bearing ancillary isocyanide ligands were obtained by the bridge-splitting reaction between the dimer [Pt(ppy)(μ-Cl)]2 and 2 equiv any one of the corresponding CNAr. Complex 2 was crystallized in two polymorphic forms, namely, 2I and 2II, exhibiting green (emission quantum yield of 0.5%) and orange (emission quantum yield of 12%) phosphorescence, respectively. Structure-directing non-covalent contacts in these polymorphs were verified by a combination of experimental (X-ray diffraction) and theoretical methods (NCIplot analysis, combined electron localization function (ELF), and Bader quantum theory of atoms in molecules (QTAIM analysis)). A noticeable difference in the spectrum of non-covalent interactions of 2I and 2II is seen in the Pt···Pt interactions in 2II and absence of these metallophilic contacts in 2I. The other solid luminophores, namely, 1, 3I-II, 4, and 4·CHCl3, exhibit green luminescence; their structures include intermolecular C-I···Cl-Pt halogen bonds as the structure-directing interactions. Crystals of 1, 2I, 3I, 3II, 4, and 4·CHCl3 demonstrated a reversible mechanochromic color change achieved by mechanical grinding (green to orange) and solvent adsorption (orange to green). | ||
| 333 | _aРежим доступа: по договору с организацией-держателем ресурса | ||
| 461 | _tACS Omega | ||
| 463 |
_tVol. 7, iss. 38 _v[P. 34454-34462] _d2022 |
||
| 610 | 1 | _aэлектронный ресурс | |
| 610 | 1 | _aтруды учёных ТПУ | |
| 701 | 1 |
_aSokolova _bE. V. _gElina Vadimovna |
|
| 701 | 1 |
_aKinzhalov _bM. A. _cchemist _cSenior Researcher, Tomsk Polytechnic University, Candidate of Chemical Sciences _f1987- _gMikhail Andreevich _2stltpush _3(RuTPU)RU\TPU\pers\47623 |
|
| 701 | 1 |
_aSmirnov _bA. S. _gAndrey Sergeevich |
|
| 701 | 1 |
_aCheranyova _bA. M. _gAnna Mikhaylovna |
|
| 701 | 1 |
_aIvanov _bD. M. _cChemist _cSenior researcher of Tomsk Polytechnic University, Candidate of chemical sciences _f1992- _gDaniil Mikhaylovich _2stltpush _3(RuTPU)RU\TPU\pers\47038 |
|
| 701 | 1 |
_aKukushkin _bV. Yu. _gVadim Yurjevich |
|
| 701 | 1 |
_aBokach _bN. A. _cChemist _cLeading researcher of Tomsk Polytechnic University, Doctor of chemical sciences _f1976- _gNadezhda Arsenjevna _2stltpush _3(RuTPU)RU\TPU\pers\47040 |
|
| 712 | 0 | 2 |
_aНациональный исследовательский Томский политехнический университет _bИсследовательская школа химических и биомедицинских технологий _bМеждународная научно-исследовательская лаборатория "Невалентные взаимодействия в химии материалов" _h8903 _2stltpush _3(RuTPU)RU\TPU\col\27854 |
| 801 | 2 |
_aRU _b63413507 _c20230628 _gRCR |
|
| 856 | 4 | _uhttps://doi.org/10.1021/acsomega.2c04110 | |
| 942 | _cCF | ||